Q. Base strength of (a) H₃C–CH₂⁻ (b) H₂C=CH⁻ (c) H–C≡C⁻ is in the order of

A) a > b > c
B) b > a > c
C) c > b > a
D) a > c > b
Explanation

[Solution from source] The conjugate acids get more acidic from ethane (sp³) to ethene (sp²) to ethyne (sp), because more s-character holds the lone pair more tightly. The stronger the conjugate acid, the weaker the base, so the basicity order is ethyl > vinyl > acetylide anion. The reverse order (acetylide strongest) is the stability order, not the base strength. Answer (1).

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

Want to attempt the full paper?
View Full Paper Take Full Paper Online