Q. Copper sulphate dissolves in excess of KCN to give :

A) CuCN
B) [Cu(CN)₄]³⁻
C) [Cu(CN)₄]²⁻
D) Cu(CN)₂
Explanation

[Solution from source] CN⁻ reduces Cu²⁺ to Cu⁺ (2Cu²⁺ + 4CN⁻ → 2CuCN + (CN)₂), and CuCN dissolves in excess cyanide to give the stable tetracyanidocuprate(I) ion, [Cu(CN)₄]³⁻. The Cu(II) complex [Cu(CN)₄]²⁻ is not the product, and CuCN is only the intermediate before excess KCN acts. Answer (2).

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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