Q.
The enthalpy and entropy change for the reaction : Br₂(l) + Cl₂(g) → 2BrCl(g) are 30 kJ mol⁻¹ and 105 J K⁻¹ mol⁻¹ respectively. The temperature at which the reaction will be in equilibrium is :
A) 285.7 K
B) 373 K
C) 250 K
D) 400 K
Explanation
[Solution from source] At equilibrium ΔG = ΔH − TΔS = 0, so T = ΔH/ΔS = 30 000 J mol⁻¹/105 J K⁻¹ mol⁻¹ = 285.7 K. Forgetting to convert kJ to J gives a meaningless 0.29 K. Answer (1).
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.