[Solution from source] The principal chain includes the –COCl carbon and has five carbons; numbering starts from that carbon (C-1). Methyl groups sit on C-2 and C-3, so the name is 2,3-dimethylpentanoyl chloride. Numbering from the other end, or choosing a four-carbon chain with an ethyl branch, breaks the IUPAC rules. Answer (4).