Q.
A solution has a 1 : 4 mole ratio of pentane to hexane. The vapour pressure of the pure hydrocarbons at 20°C are 440 mm of Hg for pentane and 120 mm of Hg for hexane. The mole fraction of pentane in the vapour phase would be :
A) 0.178
B) 0.278
C) 0.378
D) 0.478
Explanation
[Solution from source] x(pentane) = 1/5 = 0.2. p(pentane) = 0.2 × 440 = 88 mm and p(hexane) = 0.8 × 120 = 96 mm, total 184 mm. Vapour mole fraction of pentane = 88/184 ≈ 0.478. Answer (4).
Reviewed by Dr. Abubacker
Physics Educator & NEET/JEE Specialist
Ph.D. in Physics with 19+ years of teaching experience.