[Solution by Dr. Abubacker] The curve is the line $x-y=2$. The centre $(3,0)$ is at distance $\frac1{\sqrt2}$ from it, so the chord subtends $\frac\pi2$ at the centre. Smaller segment $=\frac12\left(\frac\pi2-1\right)=\frac\pi4-\frac12$; larger $=\pi-\left(\frac\pi4-\frac12\right)$. Difference $=1+\frac\pi2$. Answer (1).