[Solution by Dr. Abubacker] Let the columns be $c_1,c_2,c_3$. The first condition gives $c_2=(0,0,1)^T$. Then $4c_1+c_2+3c_3=(0,1,0)^T$ and $2c_1+c_2+2c_3=(1,0,0)^T$. Subtracting twice the second from the first: $-c_2-c_3=(-2,1,0)^T$, so $c_3=(2,-1,0)^T-c_2=(2,-1,-1)^T$. Hence $a_{23}=-1$. Answer (1).