[Solution by Dr. Abubacker] $2\text{MnO}_2+4\text{KOH}+\text{O}_2\ (\text{or KNO}_3)\to2\text{K}_2\text{MnO}_4+2\text{H}_2\text{O}$. The first step gives potassium manganate, $\text{K}_2\text{MnO}_4$, which is then oxidised/disproportionated to $\text{KMnO}_4$. Answer (4).