Q. Which one of the carbocations from the following is most stable?

A) [image:2025J24S1_Q65_opt_a.png]
B) [image:2025J24S1_Q65_opt_b.png]
C) [image:2025J24S1_Q65_opt_c.png]
D) [image:2025J24S1_Q65_opt_d.png]
Explanation

[Solution by Dr. Abubacker] The cation is allylic; the substituent on the far end of the allyl system decides stability. In option (2) the oxygen lone pair of $-OCH_3$ is directly conjugated with the allyl cation (+M effect), giving an extra oxocarbenium resonance form. In (4) the acetyl group withdraws the oxygen lone pair, in (3) $F$ is a weaker donor, and in (1) the $-CH_2OCH_3$ group is only inductively withdrawing. So (2) is the most stable. Answer (2).

Dr. Abubacker
Reviewed by Dr. Abubacker

Physics Educator & NEET/JEE Specialist

Ph.D. in Physics with 19+ years of teaching experience.

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